Shape Fluctuations of a Droplet Containing a Polymer

We consider the problem of an ideal polymer confined in a droplet. When the droplet radius is smaller than the (unconfined) polymer radius of gyration, the polymer entropy will depend on the droplet shape. We compute the resulting surface free energy. Using parameters appropriate for polymers confined in microemulsions, we find that the polymer and bending surface energies are comparable for the lowest modes. Finally, we argue that chain self-avoidance will decrease the strength of the polymer contribution to the surface energy.Comment: Revtex, 12 pages, one figur

Impacts of Protected Areas on Local Livelihoods in Cambodia

SummaryImpact evaluation methods (mixed effects models and matching) were used to investigate the effect of protected areas (PAs) on poverty and livelihoods in Cambodia, comparing households inside PAs with bordering villages and controls. There was no evidence that PAs exacerbated local poverty or reduce agricultural harvests in comparison with controls. Households bordering the PAs were significantly better off due to greater access to markets and services. Non-timber forest product (NTFP) collectors inside PAs were significantly better off than controls and had greater rice harvests, because they had more secure access to land and forest resources. The PAs in Cambodia therefore have some positive impacts on households that use forest and land resources for their livelihoods

Structure of bottle-brush brushes under good solvent conditions. A molecular dynamics study

We report a simulation study for bottle-brush polymers grafted on a rigid backbone. Using a standard coarse-grained bead-spring model extensive molecular dynamics simulations for such macromolecules under good solvent conditions are performed. We consider a broad range of parameters and present numerical results for the monomer density profile, density of the untethered ends of the grafted flexible backbones and the correlation function describing the range that neighboring grafted bottle-brushes are affected by the presence of the others due to the excluded volume interactions. The end beads of the flexible backbones of the grafted bottle-brushes do not access the region close to the rigid backbone due to the presence of the side chains of the grafted bottle-brush polymers, which stretch further the chains in the radial directions. Although a number of different correlation lengths exist as a result of the complex structure of these macromolecules, their properties can be tuned with high accuracy in good solvents. Moreover, qualitative differences with "typical" bottle-brushes are discussed. Our results provide a first approach to characterizing such complex macromolecules with a standard bead spring model.Comment: To appear in Journal of Physics Condensed Matter (2011

Fluctuations of a driven membrane in an electrolyte

We develop a model for a driven cell- or artificial membrane in an electrolyte. The system is kept far from equilibrium by the application of a DC electric field or by concentration gradients, which causes ions to flow through specific ion-conducting units (representing pumps, channels or natural pores). We consider the case of planar geometry and Debye-H\"{u}ckel regime, and obtain the membrane equation of motion within Stokes hydrodynamics. At steady state, the applied field causes an accumulation of charges close to the membrane, which, similarly to the equilibrium case, can be described with renormalized membrane tension and bending modulus. However, as opposed to the equilibrium situation, we find new terms in the membrane equation of motion, which arise specifically in the out-of-equilibrium case. We show that these terms lead in certain conditions to instabilities.Comment: 7 pages, 2 figures. submitted to Europhys. Let

Strong-Segregation Theory of Bicontinuous Phases in Block Copolymers

We compute phase diagrams for $A_nB_m$ starblock copolymers in the strong-segregation regime as a function of volume fraction $\phi$, including bicontinuous phases related to minimal surfaces (G, D, and P surfaces) as candidate structures. We present the details of a general method to compute free energies in the strong segregation limit, and demonstrate that the gyroid G phase is the most nearly stable among the bicontinuous phases considered. We explore some effects of conformational asymmetry on the topology of the phase diagram.Comment: 14 pages, latex, 21 figures, to appear in Macromolecule

Experimental Study of Parametric Autoresonance in Faraday Waves

The excitation of large amplitude nonlinear waves is achieved via parametric autoresonance of Faraday waves. We experimentally demonstrate that phase locking to low amplitude driving can generate persistent high-amplitude growth of nonlinear waves in a dissipative system. The experiments presented are in excellent agreement with theory.Comment: 4 pages, 4 eps figures, to appear in Phys. Rev. Let

One- and two-particle microrheology

We study the dynamics of rigid spheres embedded in viscoelastic media and address two questions of importance to microrheology. First we calculate the complete response to an external force of a single bead in a homogeneous elastic network viscously coupled to an incompressible fluid. From this response function we find the frequency range where the standard assumptions of microrheology are valid. Second we study fluctuations when embedded spheres perturb the media around them and show that mutual fluctuations of two separated spheres provide a more accurate determination of the complex shear modulus than do the fluctuations of a single sphere.Comment: 4 pages, 1 figur

Bigraphical Refinement

We propose a mechanism for the vertical refinement of bigraphical reactive systems, based upon a mechanism for limiting observations and utilising the underlying categorical structure of bigraphs. We present a motivating example to demonstrate that the proposed notion of refinement is sensible with respect to the theory of bigraphical reactive systems; and we propose a sufficient condition for guaranteeing the existence of a safety-preserving vertical refinement. We postulate the existence of a complimentary notion of horizontal refinement for bigraphical agents, and finally we discuss the connection of this work to the general refinement of Reeves and Streader.Comment: In Proceedings Refine 2011, arXiv:1106.348

The 2015 Sheffield System for Longitudinal Diarisation of Broadcast Media

Speaker diarisation is the task of answering "who spoke when" within a multi-speaker audio recording. Diarisation of broadcast media typically operates on individual television shows, and is a particularly difficult task, due to a high number of speakers and challenging background conditions. Using prior knowledge, such as that from previous shows in a series, can improve performance. Longitudinal diarisation allows to use knowledge from previous audio files to improve performance, but requires finding matching speakers across consecutive files. This paper describes the University of Sheffield system for participation in the 2015 Multi-Genre Broadcast (MGB) challenge. The challenge required longitudinal diarisation of data from BBC archives, under very constrained resource settings. Our system consists of three main stages: speech activity detection using DNNs with novel adaptation and decoding methods; speaker segmentation and clustering, with adaptation of the DNN-based clustering models; and finally speaker linking to match speakers across shows. The final result on the development set of 19 shows from five different television series provided a Diarisation Error Rate of 50.77% in the diarisation and linking task